New insights into carbon dioxide interactions with benzimidazole-linked polymers.
نویسندگان
چکیده
A synergistic experimental and theoretical study (DFT) highlights the impact of material design at the molecular and electronic levels on the binding affinity and interaction sites of CO2 with benzimidazole-linked polymers (BILPs); CO2 is stabilized by benzimidazole units through Lewis acid-base (N···CO2) and aryl C-H···O=C=O interactions.
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عنوان ژورنال:
- Chemical communications
دوره 50 27 شماره
صفحات -
تاریخ انتشار 2014